环境界面化学研究组课题组简介

  
环境界面化学组长期从事持久性有毒污染物的形态分析、生物有效和污染物在环境介质中的界面迁移与转化机理的研究。课题组拥有安捷伦气质联用仪，气相色谱仪（两台），高效液相色谱仪（三台）以及PCR仪，凝胶电泳仪，凝胶成像仪等实验仪器。课题组目前承担国家自然科学基金重点项目、973课题和多项自然科学基金面上项目。课题组已在SCI收录期刊发表论文200余篇。目前课题组有研究员1人、副研究员4人、助理研究员1人、博士后1人和研究生10人。

 主要研究方向：
 

   （1）环境介质中持久性有毒污染物的形态分析
    和生物有效性；

（2）持久性有毒污染物的界面迁移和转化机理；

（3）土壤中新型污染物的生物吸收和毒性效应；

（4）人工纳米材料的界面行为和植物吸收与
   传输机理。

环境界面化学研究组研究队伍

环境界面化学研究组承担项目

1.国家自然科学基金重点项目：土壤中典型有机污染物的分子转化与生物效应机制
研究，2016-2020.

2. 国家973 课题：有机污染物多介质微界面行为原位表征方法，2014-2018。

3. 中国科学院战略性先导科技专项子课题：环境污染物的生物有效性，2014-2019。

4.. 国家自然科学基金面上项目：应用同步辐射谱学技术研究典型有机污染物的土壤微界面过程，2013-2016.

5. 国家自然科学基金面上项目：纳米颗粒的植物吸收与传输机理研究，2013-2016.

6. 国家自然科学基金面上项目：复合污染条件下重金属与有机污染物在石墨烯纳米材料上的交互吸附/解吸机制研究， 2013-2016.

7. 国家自然科学基金面上项目：污泥施用农田土壤中全氟化合物在土壤-农作物系统中的积累、迁移、转化研究， 2014-2017.

8. 国家自然科学基金面上项目：溶解性有机质对典型有机污染物土壤界面过程的影响机制，2015-2018.

9. 国家自然科学基金面上项目：水溶液中石墨烯纳米材料促进有机污染物转化与降解行为研究，2015-2018.

10. 国家自然科学基金面上项目：植物中典型手性溴代阻燃剂的生物转化、毒性效应及其对映体选择性分子机制研究，2016-2019.

11. 国家自然科学基金面上项目：土壤中全氟化合物同分异构体的选择性蚯蚓积累代谢机制研究，2017-2020.

12. 国家自然科学基金青年项目：纳米颗粒对水体中可溶性有机质（DOM）化学分馏及其结构转化的影响机制，2015-2017.

环境界面化学研究组近期成果

发表论文（近五年）：

1.      Jitao Lv, Shuzhen Zhang^*, Lei Luo, Dong Cao. Solid-phase extraction-stepwise elution (SPE-SE) procedure for isolation of dissolved organic matter prior to ESI-FT-ICR-MS analysis. Analytica Chimica Acta, 10.1016/j.aca.2016.10.038.

2.     Honglin Huang, Shuzhen Zhang^*, Jitao Lv, Bei Wen, Songshan Wang, Tong Wu. Experimental and theoretical evidence for diastereomer- and enantiomer-specific accumulation and biotransformation of HBCD in maize roots. Environmental Science and Technology, 2016, DOI: 10.1021/acs.est.6b03223.

3.      Songshan Wang, Jitao Lv, Jingyuan Ma, Shuzhen Zhang^*. Cellular internalization and intracellular biotransformation of silver nanoparticles in Chlamydomonas reinhardtii. Nanotoxicology, 2016, 10, 1129−1135.

4.      Jitao Lv, Shuzhen Zhang^*, Songshan Wang, Lei Luo, Dong Cao, Peter Christie, Molecular-scale investigation with ESI-FT-ICR-MS on fractionation of dissolved organic matter induced by adsorption on iron oxyhydroxides. Environmental Science & Technology, 2016, 50, (5), 2328−36.

5.      Chuang Xu, Songshan Wang, Zien Chen, Jitao Lv, Lei Luo^*, Jumei Li, Yibing Ma. Sulphur speciation and availability in long-term fertilized soil: evidence from chemical fractionation and S K-edge XANES spectroscopy. European Journal of Soil Science, 2016, 67, 666−675.

6.     Xuehui Xu, Bei Wen, Honglin Huang, Sen Wang, Ruixia Han, Shuzhen Zhang^*. Uptake, translocation and biotransformation kinetics of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.). Environmental Pollution, 2016, 208, 714–722.

7.      Honglin Huang, Sen Wang, Jitao Lv, Xuehui Xu, Shuzhen Zhang^*. Influences of artificial root exudate components on the behaviors of BDE-28 and BDE-47 in soils: desorption, availability, and biodegradation. Environmental Science and Pollution Research, 2016, 23(8), 7702−7711.

8.      Weining Wan, Shuzhen Zhang^*, Honglin Huang, Tong Wu. Occurrence and distribution of organophosphorus esters in soils and wheat plants in a plastic waste treatment area in China. Environmental Pollution, 2016, 214, 349−353.

9.      Bei Wen^*, Yali Wu, Hongna Zhang, Yu Liu, Xiaoyu Hu, Honglin Huang, Shuzhen Zhang. The roles of protein and lipid in the accumulation and distribution of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in plants grown in biosolids-amended soil. Environmental Pollution, 2016, 216, 682−688.

10.  Tong Wu, Honglin Huang, Shuzhen Zhang^*. Accumulation and phytotoxicity of technical hexabromocyclododecane in maize. Journal of Environmental Sciences, 2016, 42, 97−104.

11.   Zien Chen, Lei Luo^*, Diyi Xiao, Jitao Lv, Ben Wen, Yibing Ma, Shuzhen Zhang. Selected dark sides of biomass-derived biochars as environmental amendments. Journal of Environmental Sciences, 2016, doi: 10.1016/j.jes.2016.06.004.

12.   Lei Luo, Chuang Xu, Zien Chen, Shuzhen Zhang^*. Properties of biomass-derived biochars: Combined effects of operating conditions and biomass types. Bioresource Technology, 2015, 192, 83−89.

13.   Hongna Zhang, Bei Wen^*, Xiaoyu Hu, Yali Wu, Lei Luo, Zien Chen, Shuzhen Zhang. Determination of perflorotelomer alcohols and their degradation products in biosolids-amended soils and plants using ultra-high performance liquid chromatography tandem mass spectrometry. Journal of Chromatography A, 2015, 1404, 72−80.

14.   Bei Wen^*, Hongna Zhang, Longfei Li, Xiaoyu Hu, Yu Liu, Xiaoquan Shan, Shuzhen Zhang. Bioavailability of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in biosolids-amended soils to earthworms (Eiseniafetida). Chemosphere, 2015, 361−366.

15.    Jitao Lv, Shuzhen Zhang^*, Lei Luo, Jing Zhang, Kang Yang, Peter Christie, Accumulation, speciation and uptake pathway of ZnO nanoparticles in maize. Environmental Science-Nano, 2015, 2(1), 68−77.

16.   Xuehui Xu, Honglin Huang, Bei Wen, Sen Wang, Shuzhen Zhang^*. Phytotoxicity of brominated diphenyl ether-47 (BDE-47) and its hydroxylated and methoxylated analogues (6-OH-BDE-47 and 6‑MeO-BDE-47) to maize (Zea mays L.). Chemical Research in Toxicology. 2015, 28, 510−517.

17.   Chunmei Li, Lingyun Li, Lixiang Sun, Zhiguo Pei^*, Jieli Xie, Shuzhen Zhang. Transformation of hydroquinone to benzoquinone mediated by reduced graphene oxide in aqueous solution, Carbon, 2015, 89, 74−81.

18.   Lei Luo, Jitao Lv, Chuang Xu, Shuzhen Zhang^*. Strategy for characterization  of distribution and associations of organobromine compounds in soil using synchrotron based spectromicroscopies. Analytical Chemistry, 2014, 86, 11002−11005.

19.    Bei Wen^*, Longfei Li, Hongna Zhang, Yibing Ma, Xiaoquan Shan, Shuzhen Zhang. Field study on the uptake and translocation of perfluoroalkyl acids (PFAAs) by wheat (Triticumaestivum L.) grown in biosolids-amended soils. Environmental Pollution, 2014, 184, 547−554.

20.  Lei Luo, Chuang Xu, Yibing Ma, Lei Zheng, Lijuan Liu, Jitao Lv, Shuzhen Zhang. Sulfur speciation in an arable soil as affected by sample pretreatments and sewage sludge application. Soil Science Society of America Journal. 2014, 78(5), 1615−1623.

21.   Jitao Lv, Shuzhen Zhang^*, Songshan Wang, Lei Luo, Honglin Huang, Jing Zhang, Chemical transformation of zinc oxide nanoparticles as a result of interaction with hydroxyapatite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 461: 126−132.

22.   ShuangYang, Lingyun Li, Zhiguo Pei^*, Chunmei Li, Xiaoquan Shan, Bei Wen, Shuzhen Zhang. Effects of humic acid on copper adsorption onto few-layer reduced graphene oxide and few-layer graphene oxide. Carbon, 2014, 75, 227−235.

23.   ShuangYang, Lingyun Li, Zhiguo Pei^*, Chunmei Li, Xiaoquan Shan, Bei Wen, Shuzhen Zhang. Adsorption kinetics, isotherms and thermodynamics of Cr(Ⅲ) on graphene oxide. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 457, 100−106.

24.   Zhiguo Pei^*, ShuangYang, Lingyun Li, Chunmei Li, Xiaoquan Shan, Shuzhen Zhang, Bei Wen. Effects of copper and aluminum on the adsorption of sulfathiazole and tylosin on peat and soil. Environmental Pollution, 2014, 184, 579-585.

25.  Sen Wang, Shuzhen Zhang^*, Honglin Huang, Zhenchuan Niu, Wei Han. Characterization of polybrominated diphenyl ethers (PBDEs) and hydroxylated and methoxylated PBDEs in soils and plants from an e-waste area, China. Environmental Pollution, 2014, 184, 405−413.

26.   王森，黄红林，张淑贞^*。土壤-植物系统中多溴联苯醚(PBDEs)的迁移与转化研究进展，环境化学, 2014, 33(10), 1645−1654。

27.   许闯，王松山，李菊梅，马义兵，孙文涛，罗磊^*，张淑贞。长期施肥对红壤和黑土硫素形态演变的影响，应用生态学报，2014，25，1069−1075

28.   Honglin Huang, Shuzhen Zhang^*, Sen Wang, Jitao Lv. In vitro biotransformation of PBDEs by root crude enzyme extracts: Potential role of nitrate reductase (NaR) and glutathione S-transferase (GST) in their debromination, Chemosphere, 2013, 90, 1885–1892

29.   Bei Wen^*, Longfei Li, Yu Liu, Hongna Zhang, Xiaoyu Hu, Xiaoquan Shan, Shuzhen Zhang. Mechanistic studies of perfluorooctane sulfonate, perfluorooctanoic acid uptake by maize (Zea mays L. cv. TY2), Plant Soil,  2013, 370, 345–354

30.   Wei Han, Lei Luo, Shuzhen Zhang^*. Adsorption of tetrabromobisphenol A on soils: Contribution of soil components and influence of soil properties, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2013, 28, 60– 64,

31.   Zhiguo Pei^*, Lingyun Li, Lixiang Sun, Shuzhen Zhang, Xiaoquan Shan, Shuang Yang, Bei Wen. Adsorption characteristics of 1,2,4-trichlorobenzene, 2,4,6- trichlorophenol, 2-naphthol and naphthalene on grapheme and graphene oxide,  Carbon, 2013, 51, 156–163

32.   Wei Han, Sen Wang, Honglin Huang, Lei Luo, Shuzhen Zhang^*. Method for simultaneous determination of brominated phenols in soils, Journal of Environmental Sciences, 2013, 25(11) 2306–2312

33.   吕继涛，张淑贞^*。人工纳米材料与植物的相互作用与植物毒性: 吸收和传输，化学进展，2013，25，156–163

34.   罗磊, 吕继涛, 许闯, 郭智, 张淑贞^*。近边X射线吸收精细结构光谱法研究土壤腐殖质组分含碳官能团组成及磷酸根影响，分析化学，2013, 41 (8)，1279–1282.

35.   Honglin Huang, Shuzhen Zhang^*, Sen Wang, Jitao Lv. In vitro biotransformation of PBDEs by root crude enzyme extracts: Potential role of nitrate reductase (NaR) and glutathione S-transferase (GST) in their debromination, Chemosphere, 2013, 90, 1885–1892.

36.   JitaoLv, Lei Luo, Jing Zhang, Peter Christie, Shuzhen Zhang^*. Adsorption of mercury on lignin: Combined Surface complexation modeling and X-ray absorption spectroscopy studies, Environmental Pollution, 2012, 162, 255–261.

37.   Moming Zhao, Shuzhen Zhang^*, Sen Wang, Honglin Huang. Uptake, translocation, and debromination of polybrominateddiphenyl ethers, Journal of Environmental Sciences, 2012, 24, 402–409.

38.   Xiuying Li, Tong Wu, Honglin Huang, Shuzhen Zhang^*. Atrazine accumulation and toxic responses in maize Zea may, Journal of Environmental Sciences, 2012, 24, 203–208.

39.    Anxiang Lu, Jihua Wang, Xiangyang Qin, Kaiyi Wang, Ping Han, Shuzhen Zhang^*. Multivariate and geostatistical analyses of the spatial distribution and origin of heavy metals in the agricultural soils in Shunyi, Beijing, China, Science of the Total Environment, 2012, 425, 66–74.

40.   Lichao Zhang, Lei Luo, Shuzhen Zhang^*. Integrated investigations on the adsorption mechanisms of fulvic and humic acids on three clay minerals, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2012, 406, 84–90.

41.   Sen Wang, Shuzhen Zhang^*, Honglin Huang, Anxiang Lu, Hua Ping. Debrominated, hydroxylated and methoxylated metabolism in maize (Zea mays L.) exposed to lesser polybrominateddiphenyl ethers (PBDEs), Chemosphere, 2012, 89, 1295–1301.

42.   JitaoLv, Shuzhen Zhang^*, Lei Luo, Wei Han, Jing Zhang, Ke Yang, and Peter Christie. Dissolution and microstructural transformation of ZnO nanoparticles under the influence of phosphate, Environmental Science & Technology, 2012, 46, 7215−7221.

43.   Lei Luo, Shu Lin, Honglin Huang, Shuzhen Zhang^*. Relationships between aging of PAHs and soil properties, Environmental Pollution, 2012, 170, 177−182.

44.   Tong Wu, Sen Wang, Honglin Huang, and Shuzhen Zhang^*. Diastereomer-specific uptake, translocation, and toxicity of hexabromocyclododecane diastereoisomers to maize, Journal of Agricultural and Food Chemistry, 2012, 60, 8528−8534.

45.   Yanping Zhou, Bei Wen^*, Zhiguo Pei, Guangcai Chen, JitaoLv, Jing Fang, Xiaoquan Shan, Shuzhen Zhang，Coadsorption of copper and perfluorooctanesulfonate onto multi-walled carbon nanotubes, Chemical Engineering Journal, 2012, 203 148–157.

46.   Bei Wen^*, Yu Liu, Peng Wang, Tong Wu, Shuzhen Zhang, Xiaoquan Shan, Jingfen Lu. Toxic effects of chlortetracycline on maize growth, reactive oxygen species generation and the antioxidant response, Journal of Environmental Sciences, 2012, 24, 1099–1105.

47.  Zhiguo Pei^*, Jingjing Kong, Xiaoquan Shan, Bei Wen. Sorption of aromatic hydrocarbons onto montmorillonite as affected by norfloxacin, Journal of Hazards Materials, 2012, 203, 137−144.

48.   Wei Han, Lei Luo, Shuzhen Zhang^*. Adsorption of bisphenol A on lignin: Effects of solution chemistry, International Journal of Environmental Science and Technology, 2012. 9, 543−548.

49.   吕继涛，张淑贞^*。环境中纳米材料的分离与分析方法，化学进展，2012, 24, 2374−2382.

50.   周艳萍，温蓓，胡晓宇，张淑贞^*。全氟化合物在阳离子表面活性剂改性碳纳米管上的吸附，环境化学，2012，31，43−49.

51.   Honglin Huang, Shuzhen Zhang^*, Peter Christie. Plant uptake and dissipation of PBDEs in the soils of eElectronic waste recycling sites, Environmental Pollution, 2011, 159, 238−243.

52.    Lei Luo, Shuzhen Zhang^*, Lichao Zhang, Peter Christie. Effect of phosphate on phenanthrene sorption in soils, Journal of Colloid and Interface Science, 2011, 353, 275–280.

53.  Lei Luo, Chenyan M, Yibing Ma, Shuzhen Zhang^*, Jitao Lv, Mingqi Cui. New insights into the sorption mechanism of cadmium on red mud, Environmental Pollution, 2011, 159, 1108–1113.

54.   Sen Wang, Shuzhen Zhang^*, Honglin Huang, Peter Christie. Behavior of decabromodiphenyl ether (BDE-209) in soil: Effects of rhizosphere and mycorrhizal colonization of ryegrass roots, Environmental Pollution, 2011, 159, 749–753.

55.  Tong Wu, Xiuying Li, Honglin Huang, Shuzhen Zhang^*. Enantioselective oxidative damage of chiral pesticide dichlorprop to maize, Journal of Agriculture and Food Chemistry, 2011, 59, 4315–4320.

56.   Yusheng Wang, Zhiguo Pei, Xiaoquan Shan^*, Guangcai Chen, Jing Zhang, Yaning Xie, Lirong Zheng. Effects of metal cations on sorption-desorption of  p-nitrophenol onto wheat ash, Journal of Environmental Sciences, 2011, 23, 112–118.

57.   Lichao Zhang, Lei Luo, Shuzhen Zhang^*. Adsorption of phenanthrene and 1,3-Dinitrobenzene on cation-modified clay minerals, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 377, 2011, 278–283.

58.   Yang Yu, Shuzhen Zhang^*, Bei Wen, Honglin Huang, Lei Luo. Accumulation and speciation of selenium in plants as affected of arbuscular mycorrhizal fungus Glomus mosseae, Biological Trace Element Research, 2011, 143, 1789–1798.

59.   Liang Liang, Lei Luo, Shuzhen Zhang^*. Adsorption and desorption of humic and fulvic acids on SiO₂ particles at nano andmicro-scales, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 384, 126–130.

60.  Sen Wang, Shuzhen Zhang^*, Honglin Huang, Moming Zhao, Jitao Lv, Uptake, translocation and metabolism of polybrominated diphenyl ethers(PBDEs) and polychlorinated biphenyls (PCBs) in maize (Zea mays L.), Chemosphere, 2011, 85, 379–385.

61.   Yang Yu, Lei Luo, Ke Yang, Shuzhen Zhang^*. Influence of mycorrhizal inoculation on the accumulation and speciation of selenium in maize growing in selenite and selenate spiked soils, Pedobiologi, 2011, 54 , 267– 272.

62.   李伟，罗磊，张淑贞^*。 应用先进光谱技术研究无机离子的环境界面化学，化学进展, 2011, 23, 2576– 2587.

63.   Sen Wang, Tong Wu, Honglin Huang, Hua Ping, Anxiang Lu, Shuzhen Zhang^*. Analysis of hydroxylated polybrominated diphenyl ethers in plant samples using ultra performance liquid chromatography-mass spectrometry, SCIENCE CHINA Chemistry, 2011, 54, 1782–1788.

64.   Liang Liang, Jitao Lv, Lei Luo, Jing Zhang, Shuzhen Zhang^*. Influences of surface-coated fulvic and humic acids on the adsorption of metal cations to SiO2 nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 389, 27–32.

65. 吕继涛，罗磊，张淑贞^*，杨科。玉米对纳米TiO₂的吸收与累积，环境化学，2011, 30(5), 903–907.

66.   王朋，温蓓，张淑贞^*。环丙沙星对玉米芽期抗氧化酶活性及自由基代谢的影响，环境化学，2011, 30(12), 2003–2008.

67.    Bei Wen^*, Rixiang Huang, Peng Wang, Yanping Zhou, Xiaoquan Shan, and Shuzhen Zhang. Effect of Complexation on the accumulation and elimination kinetics of cadmium and ciprofloxacin in the earthworm Eisenia fetida. Environmental Science & Technology, 2011, 45, 4339–4345

68.    Zhiguo Pei^*, Xiaoquan Shan, Jingjing Kong, Bei Wen, Jing Zhang, Lirong Zheng, Yaning Xie, Koen Janssens. Insight to ternary complexes of co-adsorption of norfloxacin and Cu(II) onto montmorillonite at different pH using EXAFS. Journal of Hazardous Materials, 2011, 186, 842–848.

69.    周艳萍，温蓓^*，胡晓宇，张淑贞。全氟化合物在碳纳米管上的吸附研究，环境化学，2011, 30(12), 2003–2008.

环境界面化学研究组获奖情况

2009年国家自然科学二等奖：土壤-植物系统典型污染物迁移转化与控制机制。

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